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・ Infrared cirrus
・ Infrared cleaning
・ Infrared countermeasure
・ Infrared cut-off filter
・ Infrared dark cloud
・ Infrared Data Association
・ Infrared detector
・ Infrared divergence
・ Infrared excess
・ Infrared fixed point
・ Infrared gas analyzer
・ Infrared heater
・ Infrared homing
・ Infrared interferometer spectrometer and radiometer
・ Infrared lamp
Infrared multiphoton dissociation
・ Infrared non-destructive testing of materials
・ Infrared open-path detector
・ Infrared Optical Telescope Array
・ Infrared photography
・ Infrared Physics and Technology
・ Infrared point sensor
・ Infrared Processing and Analysis Center
・ Infrared Riding Hood
・ Infrared Roses
・ Infrared safety (particle physics)
・ Infrared sauna
・ Infrared Science Archive
・ Infrared sensing in snakes
・ Infrared sensing in vampire bats


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Infrared multiphoton dissociation : ウィキペディア英語版
Infrared multiphoton dissociation

Infrared multiphoton dissociation (IRMPD) is a technique used in mass spectrometry to fragment molecules in the gas phase usually for structural analysis of the original (parent) molecule.
== How it works ==
An infrared laser is directed through a window into the vacuum of the mass spectrometer where the ions are. The mechanism of fragmentation involves the absorption by a given ion of multiple infrared photons. The parent ion becomes excited into more energetic vibrational states until a bond(s) is broken resulting in gas phase fragments of the parent ion. In the case of powerful laser pulses, the dissociation proceeds via inner-valence ionization of electrons.
IRMPD is most often used in Fourier transform ion cyclotron resonance mass spectrometry.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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